4.什么是相?其定义是?,相必须是混合物还是纯净物?相还有不是均相的么,能介绍一下么?

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匿名用户1024   2021-5-17 13:33   7862   2
大学化学上溶液的定义为:“溶液是两种及两种以上物质所形成的混合物,这些物质在分子层次上是均匀的,即分散程度达分子水平。溶液是各部分的化学组成和物理性质皆相同一个均相系统。”
问题中若其定义化学组成相同,物理性质相同,那混合物在其两种混合分子接触交界处便物理性质便不同啊?
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有关回应  16级独孤 | 2021-5-17 13:33:42 发帖IP地址来自
-具有均匀的物理和化学性质的均质部分是一个相。
-相可以是混合物(如糖水混合物),也可以是纯净物(如固态糖)。
-相都是均匀的,题中所述的均相应该是指系统:有的系统是均相系统,有的是非均相系统。而非均相系统是由几个均相系统组成的(如冰水=冰+水)。
(参考英文原文如下,欢迎指出不正之处)
A phase may be defined as a homogeneous portion of a system that has uniform physical and chemical characteristics. Every pure material is considered to be a phase; so also is every solid, liquid, and gaseous solution. For example, the sugar–water syrup solution just discussed is one phase, and solid sugar is another. Each has different physical properties (one is a liquid, the other is a solid); furthermore, each is different chemically (i.e., has a different chemical composition); one is virtually pure sugar, the other is a solution of
H2O and C12H22O11. If more than one phase is present in a given system, each will have its own distinct properties, and a boundary separating the phases will exist, across which there will be a discontinuous and abrupt change in physical and/or chemical haracteristics.
When two phases are present in a system, it is not necessary that there be a difference in both physical and chemical properties; a disparity in one or the other set of properties is sufficient. When water and ice are present in a container, two separate phases exist; they are physically dissimilar (one is a solid, the other is a liquid) but identical in chemical makeup. Also, when a substance can exist in two or more polymorphic forms (e.g., having both FCC and BCC structures), each of these structures is a separate phase because their
respective physical characteristics differ.
Sometimes, a single-phase system is termed homogeneous. Systems composed of two or more phases are termed mixtures or heterogeneous systems. Most metallic alloys and, for that matter, ceramic, polymeric, and composite systems are heterogeneous. Typically, the phases interact in such a way that the property combination of the multiphase system is different from, and more desirable than, either of the individual phases.
(引用自MATERIALS SCIENCE and ENGINEERING an introduction by William D. Callister, Jr. & David G. Rethwisch, Page 300)
3#
有关回应  16级独孤 | 2021-5-17 13:33:43 发帖IP地址来自
根据多名专家的长期讨论,相指在一个特定空间和特定时间的一个区间内确实存在的一种或者多种物质间混合或者单调的一个系统。
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